Researchers from Imperial College London and the University of Birmingham have designed a novel technique for large-scale production of graphene with real-time monitoring. The study provides a viable route for controllable and customizable mass-production which could be adopted for other 2D materials.

New techniques for continuous large-scale production of 2D nanomaterials image

Graphene is currently produced through a variety of methods, roughly divided into bottom-up and top-down approaches. Bottom-up graphene production builds layers atom-by-atom, making a high-quality product but with a drastically time-consuming process. Top-down graphene production is typically much faster and has the potential for large-scale production, but the quality is usually lower. Top-down processes begin with graphite which is split into different layers using a technique known as exfoliation. In this study, the team set out to produce a scalable method for top-down production which would result in a consistently high-quality graphene product.

The researchers used a combination of fluid dynamics, numerical simulations, and material characterizations to examine two different exfoliation approaches.



Both methods involved pumping liquids containing graphite particles through intense mixing environments, either over a rapidly rotating disc, or through a thin gap between two counter-rotating cylinders.

From this, the team were able to determine that factors such as the intensity of the mixing environment and the amount of time graphite particles spent within this environment were dominant in governing nanosheet characteristics and concentration.

The findings of this study offer a new technique for mass producing high-quality graphene that allows for real-time monitoring.

This ‘on-the-fly’ method will enable manufacturers to control the number of atomic layers in the 2D nanomaterials produced, allowing them to monitor the quality and production rates in real time.

Lead author Dr. Jason Stafford, School of Engineering at the University of Birmingham, said: "The research outcomes bring us a step closer to realizing widespread adoption of this promising class of nanomaterials in our future technologies.

"Inadequate global production and material quality are key issues, and this work opens up the possibility to rationally design and optimise production techniques at any scale.”

Co-author Professor Omar Matar, Imperial College London, added: “Our research is significant because it provides new methods for producing 2D materials on a large scale that can be customizable and enable real-time monitoring of the production process.”

This study represents important developments towards a greener future, as Dr. Camille Petit, also Imperial College London, explained: “Nanomaterials such as graphene will also become vital in supporting the transition towards a green energy supply, as they can be used to produce the components required in electronic devices, photovoltaics and batteries. As such, they must themselves be produced in a sustainable way.

“This study demonstrates how 2D materials can be produced using sustainable solvents, replacing the more traditional, toxic chemicals used, without affecting quality.”

Often graphene is produced using solvents, where many of the highest performing ones are the most toxic. The novel technique outlined in this study demonstrates success using a green solvent that can be optimized in 3% of the time required using traditional methods.

This can accelerate the design of green solvents as scientists are able to measure their performance as the graphene is being produced, rather than the traditional method which relies on removing graphene from the process and characterizing the solvents separately.

The researchers are currently working with industrial partners to maximize the impact of their work on manufacturing.

The researchers hope their study will be used as a basis for further investigations into other 2D materials where factors such as light scattering can alter the outcome.

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