Graphene and batteries

Graphene, a sheet of carbon atoms bound together in a honeycomb lattice pattern, is hugely recognized as a “wonder material” due to the myriad of astonishing attributes it holds. It is a potent conductor of electrical and thermal energy, extremely lightweight chemically inert, and flexible with a large surface area. It is also considered eco-friendly and sustainable, with unlimited possibilities for numerous applications.

In the field of batteries, conventional battery electrode materials (and prospective ones) are significantly improved when enhanced with graphene. Graphene can make batteries that are light, durable and suitable for high capacity energy storage, as well as shorten charging times. It will extend the battery’s life-time, which is negatively linked to the amount of carbon that is coated on the material or added to electrodes to achieve conductivity, and graphene adds conductivity without requiring the amounts of carbon that are used in conventional batteries.

Graphene can improve such battery attributes as energy density and form in various ways. Li-ion batteries can be enhanced by introducing graphene to the battery’s anode and capitalizing on the material’s conductivity and large surface area traits to achieve morphological optimization and performance.

It has also been discovered that creating hybrid materials can also be useful for achieving battery enhancement. A hybrid of Vanadium Oxide (VO2) and graphene, for example, can be used on Li-ion cathodes and grant quick charge and discharge as well as large charge cycle durability. In this case, VO2 offers high energy capacity but poor electrical conductivity, which can be solved by using graphene as a sort of a structural “backbone” on which to attach VO2 - creating a hybrid material that has both heightened capacity and excellent conductivity.

Another example is LFP ( Lithium Iron Phosphate) batteries, that is a kind of rechargeable Li-ion battery. It has a lower energy density than other Li-ion batteries but a higher power density (an indicator of of the rate at which energy can be supplied by the battery). Enhancing LFP cathodes with graphene allowed the batteries to be lightweight, charge much faster than Li-ion batteries and have a greater capacity than conventional LFP batteries.



In addition to revolutionizing the battery market, combined use of graphene batteries and supercapacitors could yield amazing results, like the noted concept of improving the electric car’s driving range and efficiency.

Battery basics

Batteries serve as a mobile source of power, allowing electricity-operated devices to work without being directly plugged into an outlet. While many types of batteries exist, the basic concept by which they function remains similar: one or more electrochemical cells convert stored chemical energy into electrical energy. A battery is usually made of a metal or plastic casing, containing a positive terminal (an anode), a negative terminal (a cathode) and electrolytes that allow ions to move between them. A separator (a permeable polymeric membrane) creates a barrier between the anode and cathode to prevent electrical short circuits while also allowing the transport of ionic charge carriers that are needed to close the circuit during the passage of current. Finally, a collector is used to conduct the charge outside the battery, through the connected device.

Eneloop battery design

When the circuit between the two terminals is completed, the battery produces electricity through a series of reactions. The anode experiences an oxidation reaction in which two or more ions from the electrolyte combine with the anode to produce a compound, releasing electrons. At the same time, the cathode goes through a reduction reaction in which the cathode substance, ions and free electrons combine into compounds. Simply put, the anode reaction produces electrons while the reaction in the cathode absorbs them and from that process electricity is produced. The battery will continue to produce electricity until electrodes run out of necessary substance for creation of reactions.

Battery types and characteristics

Batteries are divided into two main types: primary and secondary. Primary batteries (disposable), are used once and rendered useless as the electrode materials in them irreversibly change during charging. Common examples are the zinc-carbon battery as well as the alkaline battery used in toys, flashlights and a multitude of portable devices. Secondary batteries (rechargeable), can be discharged and recharged multiple times as the original composition of the electrodes is able to regain functionality. Examples include lead-acid batteries used in vehicles and lithium-ion batteries used for portable electronics.

Batteries come in various shapes and sizes for countless different purposes. Different kinds of batteries display varied advantages and disadvantages. Nickel-Cadmium (NiCd) batteries are relatively low in energy density and are used where long life, high discharge rate and economical price are key. They can be found in video cameras and power tools, among other uses. NiCd batteries contain toxic metals and are environmentally unfriendly. Nickel-Metal hydride batteries have a higher energy density than NiCd ones, but also a shorter cycle-life. Applications include mobile phones and laptops. Lead-Acid batteries are heavy and play an important role in large power applications, where weight is not of the essence but economic price is. They are prevalent in uses like hospital equipment and emergency lighting.

Lithium-Ion (Li-ion) batteries are used where high-energy and minimal weight are important, but the technology is fragile and a protection circuit is required to assure safety. Applications include cell phones and various kinds of computers. Lithium Ion Polymer (Li-ion polymer) batteries are mostly found in mobile phones. They are lightweight and enjoy a slimmer form than that of Li-ion batteries. They are also usually safer and have longer lives. However, they seem to be less prevalent since Li-ion batteries are cheaper to manufacture and have higher energy density.

Batteries and supercapacitors

While there are certain types of batteries that are able to store a large amount of energy, they are very large, heavy and release energy slowly. Capacitors, on the other hand, are able to charge and discharge quickly but hold much less energy than a battery. The use of graphene in this area, though, presents exciting new possibilities for energy storage, with high charge and discharge rates and even economical affordability. Graphene-improved performance thereby blurs the conventional line of distinction between supercapacitors and batteries.

Li-Polymer battery vs Supercapacitor structure

Commercial Graphene-enhanced battery products

Graphene-based batteries have exciting potential and while they are not commercially available yet, R&D is intensive and will hopefully yield results in the future.

In November 2016, Huawei unveiled a new graphene-enhanced Li-Ion battery that can remain functional at higher temperature (60° degrees as opposed to the existing 50° limit) and offers a longer operation time - double than what can be achieved with previous batteries. To achieve this breakthrough, Huawei incorporated several new technologies - including an anti-decomposition additives in the electrolyte, chemically stabilized single crystal cathodes - and graphene to facilitate heat dissipation. Huawei says that the graphene reduces the battery's operating temperature by 5 degrees.

In June 2014, US based Vorbeck Materials announced the Vor-Power strap, a lightweight flexible power source that can be attached to any existing bag strap to enable a mobile charging station (via 2 USB and one micro USB ports). the product weighs 450 grams, provides 7,200 mAh and is probably the world’s first graphene-enhanced battery.

In May 2014, American company Angstron Materials rolled out several new graphene products. The products, said to become available roughly around the end of 2014, include a line of graphene-enhanced anode materials for Lithium-ion batteries. The battery materials were named “NANO GCA” and are supposed to result in a high capacity anode, capable of supporting hundreds of charge/discharge cycles by combining high capacity silicon with mechanically reinforcing and conductive graphene.

Graphene batteries market report

Developments are also made in the field of graphene batteries for electric vehicles. Henrik Fisker, who announced its new EV project that will sport a graphene-enhanced battery, unveiled in November 2016 what is hoped to be a competitor to Tesla. Called EMotion, the electric sports car will reportedly achieve a 161 mph (259 kmh) top speed and a 400-mile electric range.

Graphene Nanochem and Sync R&D’s October 2014 plan to co-develop graphene-enhanced Li-ion batteries for electric buses, under the Electric Bus 1 Malaysia program, is another example.

In August 2014, Tesla suggested the development of a "new battery technology" that will almost double the capacity for their Model S electric car. It is unofficial but reasonable to assume graphene involvement in this battery.

UK based Perpetuus Carbon Group and OXIS Energy agreed in June 2014 to co-develop graphene-based electrodes for Lithium-Sulphur batteries, which will offer improved energy density and possibly enable electric cars to drive a much longer distance on a single battery charge.

Another interesting venture, announced in September 2014 by US based Graphene 3D Labs, regards plans to print 3D graphene batteries. These graphene-based batteries can potentially outperform current commercial batteries as well as be tailored to various shapes and sizes.

Other prominent companies which declared intentions to develop and commercialize graphene-enhanced battery products are: Grafoid, SiNode together with AZ Electronic Materials, XG Sciences, Graphene Batteries together with CVD Equipment and CalBattery.

Further reading

Latest Graphene Batteries news

China-US team uses graphene composite separator to achieve robust Li-S batteries

A team of researchers from The University of Texas at Austin and University of California in the US, along with teams from the University of Electronic Science and Technology, Hunan University and Soochow University in China, report the design of a negatively charged graphene composite separator for the effective suppression of the polysulfide shuttling effect in Li-sulfur batteries. The negatively charged 3D porous structure effectively inhibits the translocation of negatively charged polysulfide ions to enable highly robust Li-S batteries.

China-US team uses graphene composite separator to suppress polysulfide shuttling in Li-S batteries image

In their paper, the researchers show that by using a reduced graphene oxide (rGO)/sodium lignosulfonate (SL) composite on the standard polypropylene (PP) separator (rGO@SL/PP), they demonstrated a highly robust Li-S battery with a capacity retention of 74% over 1,000 cycles.

Rumors suggest that Huawei's Honor Magic 2 will use a graphene-based battery

According to the latest rumors, Huawei's upcoming Honor Magic 2 smartphone (that will be launched in December 2018) will feature a graphene-enhanced battery, made by Huawei itself. Interestingly, Huawei's graphene battery will have about 45% of the capacity compared to regular Li-Ion ones, but it will be able to charge extremely fast - in about 12 minutes (for a 3,000 mAh battery). The graphene battery is almost double that of a Li-Ion one.

These are just rumors at this stage, and we have no way to verify them. We do know that Huawei is working on graphene technologies for a long time, and has even launched a commercial graphene-enhanced battery in 2016 - in which the graphene is used to extend the battery's operational temperature range.

The Graphene Catalog - find your graphene material here

Graphene-Info's Batteries, Supercapacitors, Graphene Oxide, Lighting, Displays and Graphene Investments Market Reports updated to July 2018

Today we published new versions of all our graphene market reports. Graphene-Info provides comprehensive niche graphene market reports, and our reports cover everything you need to know about these niche markets. The reports are now updated to July 2018.

Graphene batteries market report 3D cover

The Graphene Batteries Market Report:

  • The advantages using graphene batteries
  • The different ways graphene can be used in batteries
  • Various types of graphene materials
  • What's on the market today
  • Detailed specifications of some graphene-enhanced anode material
  • Personal contact details into most graphene developers

The report package provides a good introduction to the graphene battery - present and future. It includes a list of all graphene companies involved with batteries and gives detailed specifications of some graphene-enhanced anode materials and contact details into most graphene developers. Read more here!

Versarien provides updates on several energy storage R&D fronts

Versarien LogoVersarien, the advanced materials engineering group, has provided an update on its activities in relation to graphene-enhanced power storage devices like batteries and supercapacitors. The primary goal of incorporating graphene into these devices, Versarien says, is to significantly increase power storage capacity and reduce charging times.

Versarien has been working with WMG (Warwick Manufacturing Group) and their partner companies and scientists at the universities of Warwick and Cambridge to collaborate on the production of power storage devices such as batteries and supercapacitors using Versarien's proprietary Nanene graphene nano platelets. Significant advances have been made through incorporating the Company's high quality graphene into these devices and the Company looks forward to commercial products becoming available in due course.

First Graphene and Flinders University form a new company to commercialize VFD technology

First Graphene logo imageFirst Graphene is collaborating with Flinders University to launch 2D Fluidics - a company that will aim to commercialize the Vortex Fluidic Device (VFD). 2D Fluidics is 50% owned by FGR and 50% by Flinders University’s newly named Flinders Institute for NanoScale Science and Technology.

The VFD was invented by the Flinders Institute for NanoScale Science and Technology’s Professor Colin Raston and enables new approaches to producing a wide range of materials such as graphene and sliced carbon nanotubes. The key intellectual property used by 2D Fluidics comprises two patents around the production of carbon nanomaterials, assigned by Flinders University.

Versarien - Think you know graphene? Think again!Versarien - Think you know graphene? Think again!