Researchers from The University of Manchester and Australia's Monash University have studied the effect of graphene functionalization on a vitrimer matrix (chemically crosslinked network able to undergo covalent bonds exchange reaction under a trigger). The chosen matrix was an epoxy vitrimer which, under heat, can exchange ester bonds, to be reprocessed, healed or relax stress while remaining covalently crosslinked. Existing work on vitrimer shows the aforementioned properties, so the team chose to focus on more unexploited properties of vitrimer for nanocomposites: their dissolution in an appropriate solvent to break the covalent bond under mild condition.
In the paper, the team shows that adding 4 kinds of graphene or functionalized graphene allows to tune some properties of the vitrimer matrix. After characterization, the epoxy is dissolved in ethylene glycol at 180C for 2h, the nanoparticles are subsequently separated and washed. The recovered nanoparticles are then free of any traces of epoxy, and intense characterization shows that despite some functionalization or unfunctionalization of graphene (depending of the initial graphene type used), the nanoparticles keep their core structure and could potentially be re-used in another matrix.
