Graphene supercapacitors

Graphene is a thin layer of pure carbon, tightly packed and bonded together in a hexagonal honeycomb lattice. It is widely regarded as a “wonder material” because it is endowed with an abundance of astonishing traits: it is the thinnest compound known to man at one atom thick, as well as the best known conductor. It also has amazing strength and light absorption traits and is even considered ecologically friendly and sustainable as carbon is widespread in nature and part of the human body.

Graphene is often suggested as a replacement for activated carbon in supercapacitors, in part due to its high relative surface area (which is even more substantial than that of activated carbon). The surface area is one of the limitations of capacitance and a higher surface area means a better electrostatic charge storage. In addition, graphene based supercapacitors will utilize its lightweight nature, elastic properties and mechanical strength.

Graphene-based supercapacitors are said to store almost as much energy as lithium-ion batteries, charge and discharge in seconds and maintain all this over tens of thousands of charging cycles. One of the ways to achieve this is by using a a highly porous form of graphene with a large internal surface area (made by packing graphene powder into a coin-shaped cell and then dry and press it).

What are supercapacitors?

Supercapacitors, also known as EDLC (electric double-layer capacitor) or Ultracapacitors, differ from regular capacitors in that they can store tremendous amounts of energy.

A basic capacitor usually consists of two metal plates, separated by an insulator (like air or a plastic film). During charging, electrons accumulate on one conductor and depart from the other. One side gains a negative charge while the other side builds a positive one. The insulator disturbs the natural pull of the negative charge towards the positive one, and that tension creates an electric field. Once electrons are given a path to the other side, discharge occurs.

Supercapacitors also contain two metal plates, only coated with a porous material known as activated carbon. They are immersed in an electrolyte made of positive and negative ions dissolved in a solvent. One plate is positive and the other is negative. During charging, ions from the electrolyte accumulate on the surface of each carbon-coated plate. Supercapacitors also store energy in an electric field that is formed between two oppositely charged particles, only they have the electrolyte in which an equal number of positive and negative ions is uniformly dispersed. Thus, during charging, each electrode ends up having two layers of charge coating (electric double-layer).

Supercapacitor design

Batteries and Supercapacitors

Unlike capacitors and supercapacitors, batteries store energy in a chemical reaction. This way, ions are inserted into the atomic structure of an electrode, instead of just clinging to it like in supercapacitors. This makes supercapacitors (and storing energy without chemical reactions in general) able to charge and discharge much faster than batteries. Due to the fact that a supercapacitor does not suffer the same wear and tear as a chemical reaction based battery, it can survive hundreds of thousands more charge and discharge cycles.

Supercapacitors boast a high energy storage capacity compared to regular capacitors, but they still lag behind batteries in that area. Supercapacitors are also usually more expensive per unit than batteries. Technically, it is possible to replace the battery of a cell phone with a supercapacitor, and it will charge much faster. Alas, it will not stay charged for long. Supercapacitors are very effective, however, at accepting or delivering a sudden surge of energy, which makes them a fitting partner for batteries. Primary energy sources such as internal combustion engines, fuel cells and batteries work well as a continuous source of low power, but cannot efficiently handle peak power demands or recapture energy because they discharge and recharge slowly. Supercapacitors deliver quick bursts of energy during peak power demands and then quickly store energy and capture excess power that's otherwise lost. In the example of an electric car, a supercapacitor can provide needed power for acceleration, while a battery provides range and recharges the supercapacitor between surges.

Supercapacitor vs Battery charge times

Common supercapacitor applications

Supercapacitors are currently used to harvest power from regenerative braking systems and release power to help hybrid buses accelerate, provide cranking power and voltage stabilization in start/stop systems, backup and peak power for automotive applications, assist in train acceleration, open aircraft doors in the event of power failures, help increase reliability and stability of the energy grid of blade pitch systems, capture energy and provide burst power to assist in lifting operations, provide energy to data centers between power failures and initiation of backup power systems, such as diesel generators or fuel cells and provide energy storage for firming the output of renewable installations and increasing grid stability.

Rivaling materials

Several materials exist that are researched and suggested to augment supercapacitors as much (or even more than) graphene. Among these materials are: hemp, that was used by Canadian researchers to develop hemp fibers that are at least as efficient as graphene ones in supercapacitor electrodes, Cigarette filters, which were used by Korean researchers to prepare a material for supercapacitor electrodes that exhibits a better rate capability and higher specific capacitance than conventional activated carbon and even higher than N-doped graphene or N-doped CNT electrodes.

Graphene supercapacitors commercialization

Graphene supercapacitors are already on the market, and several companies, including Skeleton Technology, the CRRC, ZapGoCharger, Angstron Materials and Sunvault Energy are developing such solutions. Read our Graphene Supercapacitors market report to learn more about this exciting market and how graphene will effect it.

Graphene supercapacitors market report

Further reading

Latest Graphene Supercapacitors news

A Swinburne project for safe and durable graphene supercapacitors gets closer to commercialization

Jun 19, 2017

Researchers at Swinburne University are progressing towards producing commercially viable, chemical-free, long-lasting, safe energy devices. The team is developing the Bolt Electricity Storage Technology (BEST) – a graphene oxide-based supercapacitor offering high performance and low-cost energy storage.

The team explains that this technology is this and environmentally friendly, and a patent was recently filed on it. It is reportedly on the brink of becoming a commercial prototype. Also stated was that investment in the technology's development will soon be under way through Graphene Solutions, a joint venture between graphite miner First Graphite Resources (FGR) and Australia-based electronics company Kremford.

Zenyatta Ventures and Lakehead University announce scale-up of GO program

Jun 16, 2017

Zenyatta Ventures has announced a program for a scaled-up production method of its graphite to graphene oxide for applications like water treatment, sensors, supercapacitors and Li‐ion batteries. The program is receiving grant funding from the Ontario Centres for Excellence (OCE) to allow a team of scientists at Lakehead University in Ontario, Canada to carry out this research.

The OCE funding helps established Ontario‐based companies develop, implement and commercialize technical innovations by supporting partnerships with publicly‐funded post‐secondary institutions. The focus of the research work will be on scaling up production methods for Zenyatta’s graphite to GO, a first critical step towards commercialization of the technology. The OCE VIP II $100,000 grant will be administered over two years and Zenyatta will be contributing $50,000 in cash and $60,000 in‐kind support to the project.

Graphene Handbook

Skeleton uses curved graphene in its new supercapacitor-based energy storage system

Jun 01, 2017

Skeleton Technologies has unveiled SkelGrid, an energy storage system for industrial power applications, based on the company's curved graphene supercapacitor technology. The system is meant to ensure reliable power quality in manufacturing plants, data centers, and more.

Skeleton Technologies' new SkelGrid system image

SkelGrid is said to provide the highest power and energy density on the market in the industry standard electrical cabinet or container format. The SkelGrid product family is based on SkelRack modules, which can be installed in industry standard 19”, 600mm deep cabinets, and in 20 or 40 ft. containers to provide short-term power at the megawatt level. The SkelGrid family has maximum power ratings ranging from 520 kW up to 1500 kW, and as a modular product, its components can be configured according to customers’ needs.

Graphene-based biological supercapacitors may enable improved pacemakers and implantable medical devices

May 24, 2017

Researchers from UCLA and the University of Connecticut have designed a biological supercapacitor which operates using ions derived from bodily fluids. The team predicts that this work could lead to longer-lasting cardiac pacemakers and other implantable medical devices.

The biosupercapacitor, which features graphene layered with modified human proteins as an electrode, could be used in next-generation implantable devices to speed bone growth, promote healing or stimulate the brain.

Zap&Go awarded with $1.6 million from the EU to continue development of its graphene supercapacitor enhanced power tools

May 23, 2017

UK-based graphene supercapacitor developer Zap&Go announced that it was awarded with a $1.6 million USD from the European Union to perfect the prototype cordless tools powered by its fast-charging graphene supercapacitors.

ZapGo graphene supercapacitor powered tool prototype (PE Europe 2017)

Zap&Go initiated a self-funded feasibility study to embed its graphene supercapacitors in cordless tools. The company says that it has received commitments from major OEMs in joint development agreements. In this new EU-funded project, Zap&Go intends to further develop its power modules and electronics, integrating them with cordless tools such as vacuum cleaners and power drills, and finally build units to conduct customer trials.

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