Researchers from the Chinese Academy of Sciences, the University of Science and Technology of China and North China University of Water Resources and Electric Power have studied the effects of irradiation defects on the work function of graphene electrodes in thermionic energy converters (TECs) and found that the generation of defects in graphene through irradiation would increase the work function and reduce the electron emission capacity.
Schematic diagram of a thermionic energy converter. (Image by ZHAO Ming)
Graphene has great potential as an electrode coating material for TECs of the microreactor, which can significantly improve the electron emission ability of electrode. Electrode materials will be exposed to irradiation by high-energy particles during TECs use. Previous studies have shown that the types of defects induced by irradiation in graphene are mainly Stone-Wales defects, doping defects, and carbon vacancies. The appearance of defects will affect the adsorption properties of alkali and alkaline earth metals on the graphene surface in the electrode gap, and then change the electron emission properties of the graphene coating.