A research team from the Korea Institute of Science and Technology (KIST) recently developed a graphene-based lithium-ion battery that is flexible enough to be stretched.
Dr. Jeong Gon Son's research team at the Photo-Electronic Hybrids Research Center at the Korea Institute of Science and Technology (KIST) developed the high-capacity, stretchable lithium-ion battery. The battery was developed by fabricating a structurally stretchable electrode consisting solely of electrode materials and then assembling it with stretchable gel electrolyte and stretchable packaging.
Rapid technological advancements in the electronics industry have led to a fast-growing market for high-performance wearable devices, such as smart bands and body-implantable electronic devices like pacemakers. These advancements have considerably increased the need for energy storage devices to be designed in flexible and stretchable forms that mimic human skin and organs.
However, it is very difficult to impart stretchability to a battery because the solid inorganic electrode material occupies most of the volume, and other components such as current collectors and separators must also be made stretchable. In addition, the problem of liquid electrolyte leakage under deformation should be solved.
In order to address these problems, Dr. Jeong Gon Son's research team at KIST focused on creating an accordion-like micro-structure, which gives structural stretchability to non-stretchable materials, and constructed a micro-inwardly curved electrode framework in a honeycomb shape. The inwardly protruded honeycomb framework consisted of graphene, which serves as a curtain, and carbon nanotubes, which formed a nano-size rope. The honeycomb-shaped composite framework, made of active materials, graphene, and carbon nanotubes, was inwardly protruded like an accordion using a radial compression process, which resulted in the creation of stretchable properties.
The electrodes developed by the research team do not contain any materials typically used for stretchability, such as rubber, that do not facilitate energy storage. All of the materials used by the research team in their newly developed battery are fully utilized in energy storage and charge transport. In fact, the stretchable battery created by the team showed an energy storage capacity (5.05 mAh/cm2) that is as high as existing non-stretchable batteries.
The KIST team developed stretchable the gel electrolytes and stretchable packaging materials, that block air and moisture, and keep the electrolytes from leaking. The resulting stretchable battery showed a high areal capacity of 5.05 mAh/cm2, superior electrochemical performance up to 50% strain under repeated (up to 500) stretch-release cycles and long-term stability of 95.7% after 100 cycles in air conditions.
Dr. Jeong Gon Son at KIST said, "The stretchable lithium-ion battery developed through this research is expected to present a new paradigm in term of stretchable energy storage systems for the further development of wearable and body-implantable electronic devices."
