Graphene and CNTs are both made of carbon atoms. A carbon nanotube can be thought of as a sheet of graphene (a hexagonal lattice of carbon) rolled into a cylinder. Accordingly, CNTs can be used as a starting point for making graphene, by “unzipping” them.
Both graphene and CNTs have exceptional mechanical and electronic properties, which can often be similar. Hence, they are often regarded as rivals for a host of similar applications. It should be noted that there is also an area of research focused on combining graphene and CNTs and using them together for various application like electronics, batteries, sensors and more.
Despite these similarities between the materials, there are still differences between them. While graphene is considered 2D, CNTs are often regarded and 1D. Also, graphene (when ideally structured with atom purity and perfect honeycomb lattice) is a zero-band-gap semiconductor, whereas single-walled CNTs show either metallic or semiconducting properties, with a bandgap that varies from zero to about 2 eV.
Working with CNTs is often considered challenging due to the intrinsic difficulty in positioning them accurately and connecting them. Graphene, which came into the scene later than veteran CNTs, can be easier to interconnect and dope, but carries its own set of challenges, like extraction, manipulation and stability burdens.
Carbon - a building block for many materials
Carbon is a non-metallic chemical element often regarded as a common element of all known life. It is the 15th most abundant element in the Earth's crust, and the fourth most abundant element in the universe by mass.
Carbon can be found in many forms, each of which has its own physical characteristics. These forms include well-known materials like diamond and graphite, that only differ in physical properties due to variations in the arrangement of atoms in their structures. Other, less well-known forms are fullerenes - spherical, closed-cage fullerenes are called buckerminsterfullerenes, or “buckyballs,” and cylindrical fullerenes are called nanotubes. Another form, composed only of carbon atoms in a flat, 2D lattice structure is called graphene. Other forms of carbon atoms arrangements exist,like amorphous carbon, Q-carbon and more.
What is graphene?
A single, 2 dimensional layer of graphite is called graphene. So, graphene is basically a sheet of carbon atoms arranged in a hexagonal layout. Graphene is considered the first 2D material ever discovered, and is also called a ”wonder material” thanks to an enormous group of properties it holds. For example, graphene is one of the strongest materials in universe, has superior thermal and optical properties, excellent tensile strength, relative transparency, amazing electrical conductivity, and impermeability to most gases and liquids and more.
Graphene’s many attributes make it an attractive material for researchers and developers, which are working hard all over the world to find endless uses for the material. Graphene’s tial is vast, and the applications include: touchscreens (for LCD or OLED displays), computer chips, batteries. energy generation, supercapacitors, medical equipment, water filters, solar cells and more.
What are carbon nanotubes?
Carbon nanotubes (often abbreviated to CNTs) are cylindrically-shaped molecules made of carbon atoms. A sheet of graphene can be rolled-up to make a carbon nanotube. CNTs can be single-walled (SWCNT) if made from one layer of carbon atoms, or multi-walled (MWCNT) when consisting of several layers of graphene sheets. In fact, carbon nanotubes come in various diameters, lengths, and functional group content which can tailor their use for specific applications.
The properties of CNTs change according to their characteristics. For instance, MWCNTs are usually conducting while SWCNTs can be electrically conducting, display the properties of a semiconductor or be non-conducting. Factors like structure, length, surface area, surface charge, size distribution, surface chemistry, and agglomeration state, as well as purity of the samples, have great impact on the properties of carbon nanotubes.
CNTs have unique mechanical, thermal andelecronic properties that make them intriguing for the development of new materials: impressive mechanical tensile strength,light-weight, good thermal conductivity and much more.
These properties make carbon nanotubes attractive for electronic devices, sensors and biosensors, transistors, batteries, hydrogen storage cells, electrical-shielding applications and more.
Carbon Nanotubes have been around since the early 1990s and already found some commercial use in the fields of engineering plastics, polymers, displays, anti corrosion paints, thin films and coatings, transparent and non-transparent conductive electrodes, coatings and anti-static packaging and more. In addition, active research is ongoing in fields like batteries, fuel cells, solar cells, water desalination and more.
However, after the initial hype, revolutions failed to happen and many gave up on CNTs. But this is not to say that they do not have actual potential and interest in them is reappearing in the research community in the last few years. As was said, they have found some uses and more are estimated to follow and the potential of CNTs is not considered to have been exhausted.
CNTs are available in bulk quantities up to metric ton quantities. Production capacities for CNTs have been scaled up considerably over the years and currently exceed several thousand tons per year. It is estimated that several CNT manufacturers have over 100 ton per year production capacity for multi walled nanotubes. It seems that the capacity for the production of MWNTs exceeds that of SWNTs, although there is an oversupply in the market. SWNTs are much more expensive and difficult to manufacture than MWCNTs, and there is not yet a distinct large-scale market for SWNTs, which is needed to drive down the production cost.
In terms of prices, SWCNTs are the most expensive type of CNTs, with a price tag of up to $100,000 per Kg - compared to around $100 per Kg for MWCNTs). Some manufacturers sell an intermediate type of CNTs, sometimes called few-wall CNTs. Prices for this type are varies, but can be about $1,000 per Kg. (estimated prices as per 2018).
The latest Graphene Carbon Nanotubes news:
Researchers at Duke University have created transistors with three carbon-based inks. The all-carbon thin-film transistors were made using crystalline nanocellulose as a dielectric, carbon nanotubes as a semiconductor, graphene as a conductor and paper as a substrate. This type of component could assist in addressing the environmental problem of accumulation of electronics that are non-recyclable.
“Silicon-based computer components are probably never going away and we don’t expect easily recyclable electronics like ours to replace the technology and devices that are already widely used,” said Professor Aaron Franklin, an electrical engineer at Duke University. “But we hope that by creating new, fully recyclable, easily printed electronics and showing what they can do, that they might become widely used in future applications.”
A research team from the Korea Institute of Science and Technology (KIST) recently developed a graphene-based lithium-ion battery that is flexible enough to be stretched.
Dr. Jeong Gon Son's research team at the Photo-Electronic Hybrids Research Center at the Korea Institute of Science and Technology (KIST) developed the high-capacity, stretchable lithium-ion battery. The battery was developed by fabricating a structurally stretchable electrode consisting solely of electrode materials and then assembling it with stretchable gel electrolyte and stretchable packaging.
Scientists in the Korea Institute of Science and Technology (KIST) have worked with graphene and carbon nanotubes to develop a working lithium-ion battery that can be stretched by up to 50% without damage to any of the components. According to the scientists, the battery represents a significant step in the development of wearable or body-implantable electronic devices.
Rather than trying to add inherently stretchable materials such as rubber to the battery components, the group focused on creating an “accordion-like” structure, adding stretchability to materials that are not inherently stretchable. Using graphene and carbon nanotubes, the scientists were able to construct a honeycomb-shaped composite framework, which was then compressed inwardly like an accordion to impart the stretchable properties.
Researchers at Aalto University, collaborating with researchers at CNRS France, have developed a graphene-carbon nanotube catalyst which gives better control over important chemical reactions for producing green technology and clean energy.
The oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) are the most important electrochemical reactions that limit the efficiencies of hydrogen fuel cells (for powering vehicles and power generation), water electrolyzers (for clean hydrogen production), and high-capacity metal-air batteries. The team has developed a new catalyst that reportedly drives these reactions more efficiently than other bifunctional catalysts currently available. The researchers also found that the electrocatalytic activity of their new catalyst can be significantly altered depending on choice of the material on which the catalyst was deposited.
Rice University scientists have developed a graphene-based epoxy for electronic applications. Epoxy combined with graphene foam invented in the Rice lab of Prof. James Tour) is reportedly substantially tougher than pure epoxy and far more conductive than other epoxy composites, while retaining the material's low density. It could improve upon epoxies in current use that weaken the material's structure with the addition of conductive fillers.
By itself, epoxy is an insulator, and is commonly used in coatings, adhesives, electronics, industrial tooling and structural composites. Metal or carbon fillers are often added for applications where conductivity is desired, like electromagnetic shielding. The trade-off, however, is that more filler brings better conductivity at the cost of weight and compressive strength, and the composite becomes harder to process. The Rice solution replaces metal or carbon powders with a 3D foam made of nanoscale sheets of graphene.