Researchers at MIT have developed a new roll-to-roll production process for large sheets of high-quality graphene, which the team says could lead to ultra-lightweight, flexible solar cells, and to new classes of light-emitting devices and other thin-film electronics.
The new manufacturing process, which the team says should be relatively easy to scale up for industrial production, involves an intermediate “buffer” layer of material that is key to the technique’s success. The buffer allows the ultrathin graphene sheet, less than a nanometer (billionth of a meter) thick, to be easily lifted off from its substrate, allowing for rapid roll-to-roll manufacturing.
Finding a way to make thin, large-area, transparent electrodes that are stable in open air has been a challenge in thin-film electronics in recent years, for a variety of applications in optoelectronic devices — things that either emit light, like computer and smartphone screens, or harvest it, like solar cells. Today’s standard for such applications is indium tin oxide (ITO), a material based on rare and expensive chemical elements.
Many research groups have worked on finding a replacement for ITO, focusing on both organic and inorganic candidate materials. Graphene has great potential for this role, but it very tricky to release CVD-grown graphene from its native copper substrate.
This release, known as graphene transfer process, tends to result in a web of tears, wrinkles, and defects in the sheets, which disrupts the film continuity and therefore drastically reduces their electrical conductivity. But with the new technology, the MIT team says, “now we are able to reliably manufacture large-area graphene sheets, transfer them onto whatever substrate we want, and the way we transfer them does not affect the electrical and mechanical properties of the pristine graphene.”
The key is the buffer layer, made of a polymer material called parylene, that conforms at the atomic level to the graphene sheets on which it is deployed. Like graphene, parylene is produced by CVD, which simplifies the manufacturing process and scalability.
As a demonstration of this technology, the team made proof-of-concept solar cells, adopting a thin-film polymeric solar cell material, along with the newly formed graphene layer for one of the cell’s two electrodes, and a parylene layer that also serves as a device substrate. They measured an optical transmittance close to 90% for the graphene film under visible light.
The prototyped graphene-based solar cell improves by roughly 36 times the delivered power per weight, compared to ITO-based state-of-the-art devices. It also uses 1/200 the amount of material per unit area for the transparent electrode. And, there is a further fundamental advantage compared to ITO: “Graphene comes for almost free,” the MIT team states.
The buffer material, parylene, is widely used in the microelectronics industry, usually to encapsulate and protect electronic devices. So the supply chains and equipment for using the material already are widespread. Of the three existing types of parylene, the team’s tests showed that one of them, which contains more chlorine atoms, was by far the most effective for this application.
The atomic proximity of chlorine-rich parylene to the underlying graphene as the layers are sandwiched together provides a further advantage, by offering a kind of “doping” for graphene, finally providing a more reliable and nondestructive approach for conductivity improvement of large-area graphene, unlike many others that have been tested and reported so far.
“The graphene and the parylene films are always face-to-face,” the researchers say. “So basically, the doping action is always there, and therefore the advantage is permanent.”