Band gap

Researchers at the Swiss École Polytechnique Fédérale de Lausanne (EPFL) and National Institute for Materials Science in Japan have developed a new technique to directly measure energy gaps and bandwidths in multilayer graphene systems, paving the way for deeper insights into exotic quantum states and future electronic devices.

When layers of graphene are stacked on top of each other and slightly rotated, the atomic lattices create a periodic interference pattern known as a moiré pattern. This pattern significantly changes the electronic behavior of the material, sometimes leading to exotic quantum phenomena like superconductivity and magnetism. However, directly probing the fine details of these quantum states has been a challenge. Understanding how electrons behave in these stacked graphene systems is crucial for designing future electronic and quantum devices. But conventional techniques struggle to precisely measure energy gaps and bandwidth—the parameters that dictate how electrons move and interact in these systems. Without a reliable method to extract this data, researchers have been piecing together the puzzle through indirect observations.

Researchers at the Georgia Institute of Technology and China's Tianjin University have created a novel functional semiconductor made from graphene, potentially opening the door to various next-gen electronics. 

This discovery comes at a time when silicon, the material from which nearly all modern electronics are made, is reaching its limit in the face of increasingly faster computing and smaller electronic devices. The semiconductor made from graphene is compatible with conventional microelectronics processing methods – a necessity for any viable alternative to silicon.

Researchers from Germany's RWTH Aachen University, Forschungszentrum Jülich and Japan's National Institute for Materials Science (NIMS) have found that bilayer graphene allows the realization of electron–hole double quantum dots that exhibit near-perfect particle–hole symmetry. Moreover, They showed that particle–hole symmetric spin and valley textures lead to a protected single-particle spin-valley blockade that will allow robust spin-to-charge and valley-to-charge conversion, which are essential for the operation of spin and valley qubits.

Quantum dots in semiconductors such as silicon or gallium arsenide are considered great candidates for hosting quantum bits in future quantum processors. The recent study essentially shows that bilayer graphene has even more to offer than other materials. The double quantum dots the researchers have created are characterized by a nearly perfect electron-hole-symmetry that allows a robust read-out mechanism – one of the necessary criteria for quantum computing. 

An international research team, that included researchers from the Harbin Institute of Technology in China, INRS in France and more, has demonstrated a novel process to modify the structure and properties of graphene. This process relied on a chemical reaction known as photocycloaddition, that modifies the bonds between atoms using ultraviolet (UV) light.

"No other material has properties similar to graphene, yet unlike semiconductors used in electronics, it lacks a band gap. In electronics, this gap is a space in which there are no energy levels that can be occupied by electrons. Yet it is essential for interacting with light," explains Professor Federico Rosei of INRS's Énergie Matériaux Télécommunications Research Centre.

A new collaborative study has reported a 17-carbon wide graphene nanoribbon and found that it has the tiniest bandgap observed so far among familiar graphene nanoribbons prepared through a bottom-up approach.

(a) Bottom-up synthesis scheme of 17-AGNR on Au(111), (b) high-resolution STM image, and (c) nc-AFM image of 17-AGNR. Image Credit: Junichi Yamaguchi, Yasunobu Sugimoto, Shintaro Sato, Hiroko Yamada.

The study is part of a project of CREST, JST Japan including Nara Institute of Science and Technology (NAIST), the University of Tokyo, Fujitsu Laboratories and Fujitsu.

A team led by Boston College researchers has used a sheet of graphene to track the electronic signals inherent in biological structures, in order to develop a platform to selectively identify deadly strains of bacteria. This effort could lead to more accurate targeting of infections with appropriate antibiotics, according to the team.

The prototype demonstrates the first selective, rapid, and inexpensive electrical detection of the pathogenic bacterial species Staphylococcus aureus and antibiotic resistant Acinetobacter baumannii on a single platform, said Boston College Professor of Physics Kenneth Burch, a lead co-author of the paper.

This is a sponsored article by Dr Richard Collins, IDTechEx

Graphene is on the cusp of significant market growth; the opportunities are exciting and diverse, each with significant potential. Graphene and 2D Materials Europe 2020 (13-14 May, Berlin) is the largest B2B event on the topic with a dedicated focus on the commercial frontiers. www.GrapheneEurope.tech

There is often confusion surrounding the types of graphene, commercial status, and their target markets. This article will briefly summarise each and showcase what to expect at this event.

Researchers at the U.S. Department of Energy's Lawrence Berkeley National Laboratory (Berkeley Lab) have designed a graphene device that switches from a superconducting material to an insulator and back again to a superconductor — all with a flip of a switch. The team shared that the device exhibits this unique versatility while being thinner than a human hair.

Views of the trilayer graphene/boron nitride heterostructure device as seen through an optical microscope. The gold, nanofabricated electric contacts are shown in yellow; the silicon dioxide/silicon substrate is shown in brown and the boron nitride flakes

"Usually, when someone wants to study how electrons interact with each other in a superconducting quantum phase versus an insulating phase, they would need to look at different materials. With our system, you can study both the superconductivity phase and the insulating phase in one place," said Guorui Chen, the study's lead author and a postdoctoral researcher in the lab of Feng Wang, who led the study. Wang, a faculty scientist in Berkeley Lab's Materials Sciences Division, is also a UC Berkeley physics professor.

Graphene Flagship partners, Université Libre de Bruxelles, University of Pisa and the University of Cambridge, in collaboration with the European Space Agency (ESA) and the Swedish Space Corporation (SSC), recently launched The Materials Science Experiment Rocket (MASER) into space. The objective is to test the printing of graphene patterns on silicon substrates in zero gravity conditions.

The experiment aims to test the possibilities of printing graphene inks in space. Studying the different self-assembly modes of graphene into functional patterns in zero-gravity will enable the fabrication of graphene electronic devices during long-term space missions, as well as help understand fundamental properties of graphene printing on Earth. This mission is also a first step towards the investigation of graphene for radiation shielding purposes, an essential requirement of manned space exploration.

Researchers from Purdue University, the University of Michigan and the Huazhong University of Science and Technology have used a technique called "laser shock imprinting" to permanently stress graphene into having a band gap, which could mean it would be possible to use it in various electronic components.

The researchers used a laser to create shock wave impulses that penetrated an underlying sheet of graphene. The laser shock stretches the graphene onto a permanent, trench-like mold. This caused the widening of band gap in graphene to a record 2.1 electronvolts. Previously, scientists achieved 0.5 electronvolts, barely reaching the benchmark to make graphene a semiconductor like silicon.