Partners of the European Project 'Graphene Flagship' at the University of Strasbourg and CNRS (France), along with an international team of collaborators, created new 'switches' that respond to light. The team combined light-sensitive molecules with layers of graphene and other 2D materials to create new devices that could be used in sensors, optoelectronics and flexible devices.
The researchers designed a molecule that can reversibly undergo chemical transformations when illuminated with ultraviolet and visible light. This molecule (a photoswitchable spiropyran) can be then attached to the surface of materials like graphene or molybdenum disulfide, thus generating an atomically precise hybrid macroscopic superlattice. When illuminated, the whole supramolecular structure experiences a collective structural rearrangement, which could be directly visualized with a sub-nanometer resolution by scanning tunneling microscopy.
More importantly, this light-induced reorganization at the molecular level induces large changes in the macroscopic electrical properties of the hybrid devices. The molecules, together with the layers of graphene and related materials, can convert single-molecule events into a spatially homogeneous switching action that generates a macroscopic electrical response.
"Thanks to this new approach, we can exploit the capacity of collective switching events occurring in superlattices of photochromic molecules assembled onto graphene and related materials to induce large scale and reversible modulation in the electrical properties of high-performance opto-electronic devices" explains Paolo Samorì, lead author of the paper. "This technology could find applications in the next generation of smart and portable electronics, with programmable properties," he adds.