Researchers at MIT and Harvard University have found that graphene can be tuned to behave at two electrical extremes: as an insulator, in which electrons are completely blocked from flowing; and as a superconductor, in which electrical current can stream through without resistance.
Researchers in the past, including this team, have been able to synthesize graphene superconductors by placing the material in contact with other superconducting metals â an arrangement that allows graphene to inherit some superconducting behaviors. In this new work, the team found a way to make graphene superconduct on its own, demonstrating that superconductivity can be an intrinsic quality in the purely carbon-based material.
The team found that when rotated at that magic angle, the two sheets of graphene exhibit nonconducting behavior, similar to an exotic class of materials known as Mott insulators. When the researchers then applied voltage, adding small amounts of electrons to the graphene superlattice, they found that, at a certain level, the electrons broke out of the initial insulating state and flowed without resistance, as if through a superconductor.
We can now use graphene as a new platform for investigating unconventional superconductivity, the team says. One can also imagine making a superconducting transistor out of graphene, which you can switch on and off, from superconducting to insulating. That opens many possibilities for quantum devices.
A material is considered an insulator if the last occupied energy band is completely filled with electrons. Electrical conductors such as metals, on the other hand, exhibit partially filled energy bands, with empty energy states which the electrons can fill to freely move. Mott insulators, however, are a class of materials that appear from their band structure to conduct electricity, but when measured, they behave as insulators. Specifically, their energy bands are half-filled, but because of strong electrostatic interactions between electrons (such as charges of equal sign repelling each other), the material does not conduct electricity. The half-filled band essentially splits into two miniature, almost-flat bands, with electrons completely occupying one band and leaving the other empty, and hence behaving as an insulator.
This means all the electrons are blocked, so it’s an insulator because of this strong repulsion between the electrons, so nothing can flow, the team explains. Why are Mott insulators important? It turns out the parent compound of most high-temperature superconductors is a Mott insulator. In other words, scientists have found ways to manipulate the electronic properties of Mott insulators to turn them into superconductors, at relatively high temperatures of about 100 Kelvin. To do this, they chemically dope the material with oxygen, the atoms of which attract electrons out of the Mott insulator, leaving more room for remaining electrons to flow. When enough oxygen is added, the insulator morphs into a superconductor. How exactly this transition occurs, the research say, has been a 30-year mystery.
In studying the electronic properties of graphene, the team began to examine simple stacks of graphene sheets. The researchers created two-sheet superlattices by first exfoliating a single flake of graphene from graphite, then carefully picking up half the flake with a glass slide coated with a sticky polymer and an insulating material of boron nitride. They then rotated the glass slide very slightly and picked up the second half of the graphene flake, adhering it to the first half. In this way, they created a superlattice with an offset pattern that is distinct from graphene’s original honeycomb lattice.
The team repeated this experiment, creating several devices, or graphene superlattices, with various angles of rotation, between 0 and 3 degrees. They attached electrodes to each device and measured an electrical current passing through, then plotted the device’s resistance, given the amount of the original current that passed through. "If you are off in your rotation angle by 0.2 degrees, all the physics is gone, the team says. No superconductivity or Mott insulator appears. So you have to be very precise with the alignment angle.
At 1.1 degrees â a rotation that has been predicted to be a magic angle â the researchers found the graphene superlattice electronically resembled a flat band structure, similar to a Mott insulator, in which all electrons carry the same energy regardless of their momentum. Imagine the momentum for a car is mass times velocity, the researchers said. If you’re driving at 30 miles per hour, you have a certain amount of kinetic energy. If you drive at 60 miles per hour, you have much higher energy, and if you crash, you could deform a much bigger object. This thing is saying, no matter if you go 30 or 60 or 100 miles per hour, they would all have the same energy.
For electrons, this means that, even if they are occupying a half-filled energy band, one electron does not have any more energy than any other electron, to enable it to move around in that band. Therefore, even though such a half-filled band structure should act like a conductor, it instead behaves as an insulator â and more precisely, a Mott insulator.
This gave the team an idea: What if they could add electrons to these Mott-like superlattices, similar to how scientists doped Mott insulators with oxygen to turn them into superconductors? Would graphene assume superconducting qualities in turn? To find out, they applied a small gate voltage to the magic-angle graphene superlattice, adding small amounts of electrons to the structure. As a result, individual electrons bound together with other electrons in graphene, allowing them to flow where before they could not. Throughout, the researchers continued to measure the electrical resistance of the material, and found that when they added a certain, small amount of electrons, the electrical current flowed without dissipating energy â just like a superconductor.
Perhaps more importantly, the researchers are able to tune graphene to behave as an insulator or a superconductor, and any phase in between, exhibiting all these diverse properties in one single device. This is in contrast to other methods, in which scientists have had to grow and manipulate hundreds of individual crystals, each of which can be made to behave in just one electronic phase.
Usually, you have to grow different classes of materials to explore each phase, the team says. We’re doing this in-situ, in one shot, in a purely carbon device. We can explore all those physics in one device electrically, rather than having to make hundreds of devices. It couldn’t get any simpler.